Search results for "Scanning force microscopy"

showing 10 items of 14 documents

Protective Effects of L- and D-Carnosine on R-Crystallin Amyloid Fibril Formation: Implications for Cataract Disease

2009

Mildly denaturing conditions induce bovine ?-crystallin, the major structural lens protein, to self-assemble into fibrillar structures in vitro. The natural dipeptide L-carnosine has been shown to have potential protective and therapeutic significance in many diseases. Carnosine derivatives have been proposed as potent agents for ophthalmic therapies of senile cataracts and diabetic ocular complications. Here we report the inhibitory effect induced by the peptide (L- and D-enantiomeric form) on ?-crystallin fibrillation and the almost complete restoration of the chaperone activity lost after denaturant and/or heat stress. Scanning force microscopy (SFM), thioflavin T, and a turbidimetry ass…

CrystallinCircular dichroismAmyloidCarnosinePeptideMicroscopy Atomic ForceBiochemistryCataractLens proteinRats Sprague-Dawleychemistry.chemical_compoundOrgan Culture TechniquesCrystallinChaperone activityAnimalsalpha-CrystallinsSFM Scanning Force Microscopychemistry.chemical_classificationDipeptideCD Circular DichroismThT Thioflavin TCalorimetry Differential ScanningDSC Differential Scanning CalorimetryCircular DichroismCarnosineStereoisomerismIn vitroeye diseasesRatsSpectrometry FluorescencechemistryBiochemistryHEPES 4-(2-Hydroxyethyl)piperazine-1-ethanesulfonic acidThioflavinCattleFemaleSpectrophotometry Ultravioletsense organsAmyloid fibrilMolecular Chaperones
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Carnosine inhibits amyloid fibril formation of alpha crystallin under destabilizing conditions

2008

SFM Scanning Force MicroscopyCD Circular DichroismThT Thioflavin THEPES 4-(2-Hydroxyethyl)piperazine-1-ethanesulfonic acidDSC Differential Scanning Calorimetry
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New perspectives for the design of molecular actuators: thermally induced collapse of single macromolecules from cylindrical brushes to spheres.

2004

chemistry.chemical_classificationNanostructureMaterials sciencechemistryCollapse (topology)SPHERESNanotechnologyGeneral ChemistryScanning Force MicroscopyPolymerActuatorCatalysisMacromoleculeAngewandte Chemie (International ed. in English)
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Temperature and pressure dependence of quercetin-3-O-palmitate interaction with a model phospholipid membrane: film balance and scanning probe micros…

2004

The molecular interaction of quercetin-3-O-palmitate (QP) with dimyristoylphosphatidylcholine (DMPC) has been studied. Film balance measurements of the average molecular area vs QP molar fraction in DMPC/QP mixed monolayers showed that relevant positive deviations from ideality, i.e., a less dense monolayer packing, occurred for a temperature of 10 degrees C, below the critical melting transition temperature of DMPC monolayers T c m approximately equal 20 degrees C), while ideal behavior was observed at 37 degrees C, above this phase transition temperature. The positive deviation observed at low temperatures in the average molecular area increased with the surface pressure. Scanning probe m…

Membrane FluiditySurface PropertiesLipid BilayersAnalytical chemistryPhospholipidPalmitic AcidPhase separationPalmitic AcidsSurface pressureMole fractionMicroscopy Atomic ForcePhase TransitionBiomaterialsScanning probe microscopychemistry.chemical_compoundMembrane LipidsColloid and Surface ChemistryMonolayerLangmuir-Blodgett monolayersMolecular StructureTransition temperatureTemperatureQuercetin palmitateSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsLangmuir–Blodgett monolayerMembranechemistryAluminum SilicatesQuercetinMicaStress MechanicalDimyristoylphosphatidylcholineAlgorithmsScanning force microscopy
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Nanoscale control in organic bulk heterojunctions of new set of materials for photovoltaic applications

2008

Organic PhotovoltaicScanning Force Microscopy (SFM)Solar EnergyConductive Polymers
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Inhibition of α-crystallin amyloid fibrils formation by carnosine

2008

SFM Scanning Force MicroscopyCD Circular DichroismThT Thioflavin THEPES 4-(2-Hydroxyethyl)piperazine-1-ethanesulfonic acidDSC Differential Scanning Calorimetry
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Boramers for Photovoltaic Applications

2008

Organic PhotovoltaicScanning Force Microscopy (SFM)Solar EnergyConductive Polymers
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Assembly of modular asymmetric organic-inorganic polyoxometalate hybrids into anisotropic nanostructures.

2010

Three organic-inorganic hybrid Mn-Anderson polyoxometalates (POMs), with both symmetrical and asymmetrical appended groups, have been synthesized, identified using electrospray mass spectrometry, and isolated using an approach that allows the three AA, BB, and AB compounds to be structurally characterized. Investigation of the self-assembly of the hybrids on hydrophilic surfaces reveals the formation of nanofibres with characteristics that reflect the nature of the substitution of the POM yielding a route to the programmed assembly of anisotropic hybrid nanostructures.

Models MolecularNanostructureElectrospray mass spectrometryChemistryGeneral ChemistryTungsten CompoundsBiochemistryCatalysisMass SpectrometryNanostructuresSelf-assembly Langmuir-Blodgett Scanning Force Microscopy Polyoxomethalates Hybrid Anysotropic NanostructuresColloid and Surface ChemistryChemical engineeringInorganic ChemicalsPolyoxometalateOrganic inorganicOrganic chemistryAnisotropyOrganic ChemicalsAnisotropySettore CHIM/02 - Chimica FisicaHybridJournal of the American Chemical Society
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Solution processed pentacene thin films: new routes for building-up plastic field effect transistors

2008

Plastic ElectronicScanning Force MicroscopyOrganic Semiconductors
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Effect of the heat treatment on α-crystallin : characterisation of amyloid fibrils formation and inhibitory effect of carnosine

2009

SFM Scanning Force MicroscopyCD Circular DichroismThT Thioflavin THEPES 4-(2-Hydroxyethyl)piperazine-1-ethanesulfonic acidDSC Differential Scanning Calorimetry
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